Following the announcement of England's final two matches of 2013, The FA can confirm Denmark will be the first visitors to Wembley in 2014.
England will take on Denmark on Wednesday 5 March, as part of the agreement that saw the Three Lions travel to Copenhagen in February 2011.
Goals from Ashley Young and Darren Bent secured a 2-1 victory in the Parken Stadium on that occasion.
Overall England have the better record of the two sides, with eleven wins from 18 meetings, including a World Cup second round match in Japan eleven years ago.
For details on how to buy tickets to see England face Chile and Germany in November, visit TheFA.com/Tickets